Table 1.
case | conditions | entropic driving force | label | extrema at stationary position |
||
---|---|---|---|---|---|---|
equilibrium systems (kdϕeq = d(G/T) ≤ 0) | ||||||
E1 | dS* ≥ 0, | δσ ≥ 0 | universal | panentropic | max S*, | max σ (= min H/T) |
E2 | dS* ≥ |δσ| ≥ 0, | δσ ≤ 0 | internal dominant | endoentropic | max S*, | min σ (= max H/T) |
E3 | dS* ≤ 0, | δσ ≥ |dS*| ≥ 0 | external dominant | exoentropic | min S*, | max σ (= min H/T) |
steady-state systems (Kdϕst≤ 0 with K = k/θ) | ||||||
S1 | , | universal | panentropogenic | max , | max | |
S2 | , | internal dominant | endoentropogenic | max , | min | |
S3 | , | external dominant | exoentropogenic | min , | max |