Table 4.
Partial pressures of MGD
Experiment | Int abs, cm-1 | N/v, molecule cm-3 | PMGD, atm |
1 | 0.172 | 2.65 × 1014 | 1.08 × 10-5 |
2 | 0.169 | 2.60 × 1014 | 1.06 × 10-5 |
3 | 0.171 | 2.63 × 1014 | 1.07 × 10-5 |
4 | 0.505 | 7.78 × 1014 | 3.16 × 10-5 |
Partial pressures of MGD, PMGD, determined from experimental spectra. Integrated absorbance (Int abs) for the MGD Fr OH stretch at 3,585 cm-1 was taken. Theoretically calculated σOH of 9.14 × 10-18 cm molecule-1 is used.