Table 2.
isotherm parameters |
diffusion coefficienta |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
tolueneb |
o-xyleneb |
PCEc |
toluene | o-xylene | PCE | ||||||
material | particle density (g cm–3) | mean particle diameter (µm) | K | nd | K | nd | K | nd | D | D | D |
HDPE | 0.962 | 500 | 70.7e | 1.0 | 244.1 | 1.0 | 385 | 1.0 | 3.13 × 10–10 | 2.20 × 10–10 | 1.42 × 10–10 |
PVC | 1.4 | 140 | 1663f | 0.864 | 4634 | 0.718 | 2951 | 0.918 | 4.33 × 10–13 | 4.22 × 10–14 | 1.50 × 10–14 |
acm2 s−1.
bValues from Wu et al. (2001).
cValues from Wagner (2003).
dDimensionless Freundlich exponent.
eKp for HDPE (µg kg−1)(l µg−1).
fKf for PVC (µg kg−1)(l µg−1)n.