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. 2010 Apr 6;6:32. doi: 10.3762/bjoc.6.32

Table 12.

Binding constants and enantiomeric distinction factors of chiral porphyrin-amino-acid dipeptide receptors in chloroform at 20 °C.

Guest Kass [M−1], 192a KR/KS Kass [M−1], 192b KR/KS

S-Ala-OMe 320 1.4 155.2 ± 12 3.1
R-Ala-OMe 450 488.6 ± 20
S-Val-OMe 621 1.2 175.2 ± 10 2.9
R-Val-OMe 713 502.2 ± 15
S-Leu-OMe 1030 1.2 179.8 ± 13 4.9
R-Leu-OMe 1290 881.5 ± 22
S-Phe-OMe 679 2.2 420.7 ± 10 1.1
R-Phe-OMe 1490 442.3 ± 10
S-Thr-OMe n.d. n.d. 537.6 ± 15 2.6
R-Thr-OMe n.d. 1391.3 ± 25