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. Author manuscript; available in PMC: 2011 May 20.
Published in final edited form as: J Phys Chem B. 2010 May 20;114(19):6636–6641. doi: 10.1021/jp100082n

Table 2.

Glyn frequencies and full-width-at-half-maximum (w) of the CαH2 symmetric (νsCH2) and asymmetric (νasCH2) stretching bands in solution and solid state.

polygly in 9 M LiCl solution solid polygly, mostly PGII solid polygly, mostly PGI gly5, PGI crystal
ν/cm−1 w/cm−1 ν/cm−1 w/cm−1 ν/cm−1 w/cm−1 ν/cm−1 w/cm−1
νsCH2 2937 27 2936 32 2924 19 2929 21
νasCH2 2976 35 2976 30 2948 25 2950 13