Table 2.
Glyn frequencies and full-width-at-half-maximum (w) of the CαH2 symmetric (νsCH2) and asymmetric (νasCH2) stretching bands in solution and solid state.
| polygly in 9 M LiCl solution | solid polygly, mostly PGII | solid polygly, mostly PGI | gly5, PGI crystal | |||||
|---|---|---|---|---|---|---|---|---|
| ν/cm−1 | w/cm−1 | ν/cm−1 | w/cm−1 | ν/cm−1 | w/cm−1 | ν/cm−1 | w/cm−1 | |
| νsCH2 | 2937 | 27 | 2936 | 32 | 2924 | 19 | 2929 | 21 |
| νasCH2 | 2976 | 35 | 2976 | 30 | 2948 | 25 | 2950 | 13 |