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. 2010 May 28;7(3):136–146. doi: 10.7150/ijms.7.136

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© Ivyspring International Publisher. This is an open-access article distributed under the terms of the Creative Commons License (http://creativecommons.org/licenses/by-nc-nd/3.0/). Reproduction is permitted for personal, noncommercial use, provided that the article is in whole, unmodified, and properly cited.

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(Scheme 3) Shows the reaction of Reppe anhydride 7 after 1,3-dipolar cycloaddition reaction of the Boc protected N-1.3.-diamino propane linker substituted glycine 9 with the Gd_xSc_3-xN@C₈₀ 8. The product 11 acts as the dienophile reaction partner with diene tetrazine-NLS-S^∩S-CPP conjugate 13 in the final DAR_inv. as pointed out in Figure 5/scheme 5).