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. Author manuscript; available in PMC: 2011 Aug 1.
Published in final edited form as: Coord Chem Rev. 2010 Aug 1;254(15-16):1769–1802. doi: 10.1016/j.ccr.2009.12.023

Table 4.1.

Reorganization energies (eV) of [Ru(NH3)5pyCH2NHCO(CH2)15SH]2+/HO2C(CH2)15SH monolayers Calculated λo was determined using Eq. 2.10. Reproduced from reference [74].

Anodic λ Cathodic λ Calculated λo
H2O 0.9 0.8 0.92
DMSO 0.9 0.7 0.75
acetonitrile 0.9 0.7 0.91
DMF 0.9 0.7 0.9
methanol 0.9 0.7 0.92
ethanol 0.9 0.7 0.85
acetone 0.9 0.7 0.84
propanol 0.6–0.7 0.6 0.81
butanol 0.6 0.5 0.78
THF 0.6 0.5 0.67