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Influence of BMOB on the sBMO complex. (a) Titration of BMOB into a fixed concentration of BMOH during steady-state nitrobenzene oxidation. (b) The energetic difference (in kcal mol−1) between alcohol binding to the BMOH–BMOB complex and to BMOH alone for primary alcohols (shaded bars) and for secondary alcohols with the hydroxyl group at the second carbon position (white bars). Positive values indicate weaker binding without BMOB. Error bars represent sd from three replicates.
