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A scatter plot of the ΔH0, nL−1, and nD−1 versus the number of primary amines per dendrimer. Smaller dendrimers (< G7) had (A) maximum heat release and (B) binding stoichiometries proportional to the number of primary amines per dendrimer. The binding of larger dendrimers (> G7) required fewer lipids and provided less enthalpy release per primary amine presumably due to the increasing density of primary amines on the dendrimer surface and steric limitations.
