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. Author manuscript; available in PMC: 2011 Jun 9.
Published in final edited form as: J Am Chem Soc. 2010 Jun 9;132(22):7645–7655. doi: 10.1021/ja910290c

Table 1.

Au-Catalyzed Cycloisomerization of Allenyl Ketones 4

graphic file with name nihms207351t1.jpg

Entry Substrate Product 2,%a
1 graphic file with name nihms207351t2.jpg graphic file with name nihms207351t3.jpg 2a, 90
2 graphic file with name nihms207351t4.jpg graphic file with name nihms207351t5.jpg 2b, 80
3 graphic file with name nihms207351t6.jpg graphic file with name nihms207351t7.jpg 2c, 82
4 graphic file with name nihms207351t8.jpg graphic file with name nihms207351t9.jpg 2d, 87
5 graphic file with name nihms207351t10.jpg graphic file with name nihms207351t11.jpg 2e, 82 (73)b
[77]c
a

Isolated yield of product for reactions performed on 0.5 mmol scale.

b

Isolated yield of 2e for reaction performed in MeNO2.

c

Isolated yield of 2e for reaction performed with 1 mol % of catalyst.