Table 3.

Selected bond lengths (Å) and bond angles (°) for 4·MeOH

Bond lengths
Re(1)–O(1)	1.701(6)	Re(1)–S(1)	2.306(2)
Re(1)–O(3)	2.032(6)	N(1)–C(7)	1.312(11)
Re(1)–N(1)	2.063(7)	N(1)–C(8)	1.442(10)
Re(1)–O(2)	2.080(6)	N(2)–C(20)	1.322(11)
Re(1)–N(2)	2.134(7)	N(2)–C(21)	1.420(11)
Bond angles
O(1)–Re(1)–O(3)	167.4(3)	O(3)–Re(1)–S(1)	88.6(2)
O(1)–Re(1)–N(1)	99.5(3)	N(1)–Re(1)–S(1)	84.1(2)
O(3)–Re(1)–N(1)	87.5(3)	O(2)–Re(1)–S(1)	167.2(2)
O(1)–Re(1)–O(2)	90.4(3)	N(2)–Re(1)–S(1)	95.71(19)
O(3)–Re(1)–O(2)	78.8(2)	C(7)–N(1)–C(8)	121.0(7)
N(1)–Re(1)–O(2)	92.9(3)	C(7)–N(1)–Re(1)	121.4(6)
O(1)–Re(1)–N(2)	91.3(3)	C(8)–N(1)–Re(1)	117.4(6)
O(3)–Re(1)–N(2)	81.4(3)	C(20)–N(2)–C(21)	106.4(7)
N(1)–Re(1)–N(2)	169.0(3)	C(20)–N(2)–Re(1)	125.1(6)
O(2)–Re(1)–N(2)	84.8(2)	C(21)–N(2)–Re(1)	128.3(5)
O(1)–Re(1)–S(1)	102.4(2)