Table 4.

Selected bond lengths (Å) and bond angles (°) for 5·CH₂Cl₂

Bond lengths
Re(1)–O(1)	1.693(6)	N(1)–C(7)	1.313(12)
Re(1)–O(3)	1.980(6)	N91)–N(2)	1.421(10)
Re(1)–N(1)	2.031(8)	N(2)–C(8)	1.295(12)
Re(1)–O(2)	2.066(6)	N(3)–C(22)	1.315(12)
Re(1)–N(3)	2.166(8)	N(3)–C(23)	1.428(11)
Re(1)–S(1)	2.329(3)
Bond angles
O(1)–Re(1)–O(3)	166.8(3)	O(3)–Re(1)–S(1)	91.6(2)
O(1)–Re(1)–N(1)	98.4(3)	N(1)–Re(1)–S(1)	82.2(2)
O(3)–Re(1)–N(1)	90.0(3)	O(2)–Re(1)–S(1)	170.2(2)
(O(1)–Re(1)–O(2)	89.4(3)	N(3)–Re(1)–S(1)	98.6(2)
O(3)–Re(1)–O(2)	80.1(3)	C(7)–N(1)–N(2)	113.4(8)
N(1)–Re(1)–O(2)	92.4(3)	C(7)–N(1)–Re(1)	124.0(7)
O(1)–Re(1)–N(3)	90.2(3)	N(2)–N(1)–Re(1)	122.6(6)
O(3)–Re(1)–N(3)	81.0(3)	C(8)–N(2)–N(1)	112.8(8)
N(1)–Re(1)–N(3)	171.0(3)	C(22)–N(3)–C(23)	107.6(8)
O(2)–Re(1)–N(3)	85.4(3)	C(22)–N(3)–Re(1)	126.3(6)
O(1)–Re(1)–S(1)	99.5(2)	C(23)–N(3)–Re(1)	125.9(6)