Table III.

Release Kinetics and Parameters of the Beads (Data Represents Mean ± SD (N = 3))

Variables	Values	SQRT (R 2)	Zero order (R 2)	Time (h)i
				T 75	T 50	T 25
Cross-linking agent	Zn	0.980	0.997	3.48 ± 0.21a	6.37 ± 0.20a	9.26 ± 0.27a
	Ca	0.972j	0.923	2.18 ± 0.17	4.27 ± 0.15	7.04 ± 0.08
Cross-linking pH	1.5	0.980	0.997	3.48 ± 0.21b	6.37 ± 0.20b	9.26 ± 0.27b
	6.3	0.989j	0.942	1.62 ± 0.02	3.16 ± 0.02	5.23 ± 0.03
Zinc acetate concentration (%)	1	0.992j	0.982	1.23 ± 0.23c	3.30 ± 0.24c	6.38 ± 0.18c
	2.5	0.986	0.995	2.82 ± 0.36	5.29 ± 0.34d	7.75 ± 0.31d
	5	0.980	0.997	3.48 ± 0.21	6.37 ± 0.20	9.26 ± 0.27
	10	0.976	0.998	3.46 ± 0.42	6.31 ± 0.47	9.16 ± 0.52
Cross-linking time (h)	0.25	0.989	0.990	1.96 ± 0.41e	4.80 ± 0.27e	7.64 ± 0.18e
	0.5	0.980	0.997	3.48 ± 0.21	6.37 ± 0.20	9.26 ± 0.27
	2	0.964	0.995	3.51 ± 0.33	6.52 ± 0.22	9.53 ± 0.36
	24	0.974	0.988	3.41 ± 0.28	6.41 ± 0.23	9.41 ± 0.19
Drying	RT	0.980	0.997	3.48 ± 0.21	6.37 ± 0.20	9.26 ± 0.27
	37°C	0.979	0.998	3.47 ± 0.13	6.33 ± 0.03	9.20 ± 0.18
	50°C	0.975	0.992	3.53 ± 0.11	6.41 ± 0.19	9.28 ± 0.27
	FD	0.913k	0.821k	–	–	–
Pectin concentration (%)	3	0.988	0.992	2.82 ± 0.42f	5.70 ± 0.32	8.58 ± 0.22
	4	0.986	0.987	3.00 ± 0.19	5.95 ± 0.35	8.90 ± 0.52
	5	0.980	0.997	3.48 ± 0.21	6.37 ± 0.20	9.26 ± 0.27
	6	0.971	0.998	3.51 ± 0.09	6.39 ± 0.18	9.27 ± 0.35
Pectin-Resveratrol	1:1	0.994j	0.972	1.95 ± 0.27g	3.94 ± 0.27g	6.63 ± 0.21g
	2:1	0.979	0.996	2.61 ± 0.08	5.33 ± 0.11	8.05 ± 0.16
	3:1	0.980	0.997	3.48 ± 0.21	6.37 ± 0.20	9.26 ± 0.27
	4:1	0.982	0.994	4.10 ± 0.14	7.43 ± 0.21	10.76 ± 0.29
Enzyme	–	0.994j	0.967	2.02 ± 0.23h	4.20 ± 0.28h	7.17 ± 0.31h

^a p < 0.05 between cross-linking agent Zn and Ca

^b p < 0.05 between cross-linking pH 1.5 and 6.3

^c p < 0.05 between zinc acetate concentration 1% with 2.5%, 5%, and 10%

^d p < 0.05 between zinc acetate concentration 2.5% with 5% and 10%

^e p < 0.05 between cross-linking time 0.25 h with 0.5, 2, and 24 h

^f p < 0.05 between pectin concentration 3% and 6%

^g p < 0.05 among pectin to resveratrol ratio 1:1, 2:1, 3:1, and 4:1

^h p < 0.05 between enzyme and nonenzyme treatment

ⁱData represents mean ± SD

^jRelease data more appropriately fit with square root of time equation

^kRelease data does not fit with both equations