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. Author manuscript; available in PMC: 2011 Jun 30.

Published in final edited form as: J Am Chem Soc. 2010 Jun 30;132(25):8635–8644. doi: 10.1021/ja100366c

Main: Arrhenius plot of ln k_sd vs. 1/T for 1 (●) and d₃₆-1 (). Inset: Variation in the KIE upon self-decay of 1 as a function of temperature, derived from fitting to the Arrhenius plot.

Inline graphic — Main: Arrhenius plot of ln k_sd vs. 1/T for 1 (●) and d₃₆-1 (). Inset: Variation in the KIE upon self-decay of 1 as a function of temperature, derived from fitting to the Arrhenius plot.