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. Author manuscript; available in PMC: 2010 Jul 14.
Published in final edited form as: J Am Chem Soc. 2009 Jul 8;131(26):9413–9425. doi: 10.1021/ja902324j

Table 2.

Screening substrates and conditions for epoxide opening.

graphic file with name nihms214818f12.jpg
a

2.5 equiv of i-PrMgBr; 1 equiv of CuX; epoxide source for entries 1–4 is (R)-propylene oxide and for entry 5 is (S)-propylene oxide.

b

Conversion.

c

Isolated yield in parentheses.

d

Inseparable byproducts.