Table 2.
Selected bond distances (Å) and angles (°) for [Yb(NO3)2L](NO3)·2MeOH (4).
| Bond distances | |||||
|
| |||||
| Yb(1)–N(2) | 2.410(3) | Yb(1)–O(6) | 2.424(2) | ||
| Yb(1)–O(4) | 2.425(2) | Yb(1)–O(1) | 2.428(2) | ||
| Yb(1)–N(3) | 2.433(3) | Yb(1)–O(2) | 2.439(2) | ||
| Yb(1)–O(7) | 2.477(2) | Yb(1)–N(1) | 2.531(3) | ||
| Yb(1)–N(4) | 2.538(2) | Yb(1)–O(3) | 2.543(2) | ||
| Yb(1)–N(6) | 2.878(2) | Yb(1)–N(5) | 2.909(3) | ||
|
| |||||
| Bond angles | |||||
|
| |||||
| N(2)–Yb(1)–O(6) | 72.51(8) | N(2)–Yb(1)–O(4) | 116.04(8) | ||
| O(6)–Yb(1)–O(4) | 140.00(7) | N(2)–Yb(1)–O(1) | 131.78(8) | ||
| O(6)–Yb(1)–O(1) | 76.60(8) | O(4)–Yb(1)–O(1) | 69.55(7) | ||
| N(2)–Yb(1)–N(3) | 160.59(8) | O(6)–Yb(1)–N(3) | 115.07(8) | ||
| O(4)–Yb(1)–N(3) | 70.63(8) | O(1)–Yb(1)–N(3) | 67.34(8) | ||
| N(2)–Yb(1)–O(2) | 67.19(8) | O(6)–Yb(1)–O(2) | 69.61(7) | ||
| O(4)–Yb(1)–O(2) | 78.14(8) | O(1)–Yb(1)–O(2) | 67.75(8) | ||
| N(3)–Yb(1)–O(2) | 131.79(8) | N(2)–Yb(1)–O(7) | 113.47(7) | ||
| O(6)–Yb(1)–O(7) | 52.03(7) | O(4)–Yb(1)–O(7) | 129.66(8) | ||
| O(1)–Yb(1)–O(7) | 71.37(7) | N(3)–Yb(1)–O(7) | 65.75(7) | ||
| O(2)–Yb(1)–O(7) | 114.18(7) | N(2)–Yb(1)–N(1) | 65.39(8) | ||
| O(6)–Yb(1)–N(1) | 76.95(8) | O(4)–Yb(1)–N(1) | 143.01(8) | ||
| O(1)–Yb(1)–N(1) | 139.88(8) | N(3)–Yb(1)–N(1) | 98.00(9) | ||
| O(2)–Yb(1)–N(1) | 128.01(8) | O(7)–Yb(1)–N(1) | 68.60(8) | ||
| N(2)–Yb(1)–N(4) | 98.28(8) | O(6)–Yb(1)–N(4) | 145.03(7) | ||
| O(4)–Yb(1)–N(4) | 74.70(7) | O(1)–Yb(1)–N(4) | 127.32(8) | ||
| N(3)–Yb(1)–N(4) | 64.96(9) | O(2)–Yb(1)–N(4) | 138.96(7) | ||
| O(7)–Yb(1)–N(4) | 106.83(7) | N(1)–Yb(1)–N(4) | 68.74(8) | ||
| N(2)–Yb(1)–O(3) | 67.07(8) | O(6)–Yb(1)–O(3) | 131.84(7) | ||
| O(4)–Yb(1)–O(3) | 51.21(8) | O(1)–Yb(1)–O(3) | 112.70(7) | ||
| N(3)–Yb(1)–O(3) | 111.73(8) | O(2)–Yb(1)–O(3) | 71.32(7) | ||
| O(7)–Yb(1)–O(3) | 174.40(7) | N(1)–Yb(1)-O(3) | 107.42(8) | ||
| N(4)–Yb(1)–O(3) | 67.71(7) | N(2)–Yb(1)–N(6) | 93.83(7) | ||
| O(4)–Yb(1)–N(6) | 140.30(7) | O(1)–Yb(1)–N(6) | 71.05(7) | ||
| N(3)–Yb(1)–N(6) | 90.01(8) | O(2)–Yb(1)–N(6) | 91.46(7) | ||
| N(1)–Yb(1)–N(6) | 71.87(8) | N(4)–Yb(1)–N(6) | 128.73(7) | ||
| O(3)–Yb(1)–N(6) | 57.89(7) | N(2)–Yb(1)–N(5) | 91.86(8) | ||
| O(6)–Yb(1)–N(5) | 143.58(7) | O(1)–Yb(1)–N(5) | 91.67(7) | ||
| N(3)–Yb(1)–N(5) | 90.64(8) | O(2)–Yb(1)–N(5) | 74.03(7) | ||
| O(7)–Yb(1)–N(5) | 154.67(7) | N(1)–Yb(1)–N(5) | 126.83(8) | ||
| N(4)–Yb(1)–N(5) | 68.13(7) | N(6)–Yb(1)–N(5) | 160.92(7) | ||
|
| |||||
| Structural characteristics of H-bonds | |||||
|
| |||||
| D–H⋯A | d(D–H) | d(H ⋯ A) | d(D ⋯ A) | <(DHA) | |
| O(12)–H(4S) ⋯ O(11) | 1.00(8) | 1.89(8) | 2.828(4) | 156(7) | |
| O(13)–H(8S) ⋯ O(12)#1 | 0.98(5) | 1.79(5) | 2.758(4) | 170(5) | |
Symmetry transformations used to generate equivalent atoms: #1 –x + 2, y − (1/2), −z + (3/2).