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. Author manuscript; available in PMC: 2011 Jun 23.
Published in final edited form as: J Am Chem Soc. 2010 Jun 23;132(24):8359–8371. doi: 10.1021/ja910369c

Figure 12.

Figure 12

(a) The triplet reactant results in an unfavorable Mo(V) site with a ligand radical and (b) intersystem crossing between the triplet and singlet surfaces is inefficient due to poor spin-orbit coupling (S.O.C.).