Table 1.
1H NMR (CDCl3) data for 7a and related complexes.
Compound | δ (ppm), Ru=CHAr | δ (ppm), ArCH3 |
---|---|---|
7a | 18.56 (s, 1H) | 2.60 (s, 3H), 2.41 (s, 3H), 2.28 (s, 3H), 2.25 (s, 3H), 2.19 (s, 3H), 2.00 (s, 3H), 1.46 (s, 3H), 1.04 (s, 3H) |
7a [17] | 19.42 (s, 1H) | 2.49 (s, 6H), 2.31 (s, 3H), 2.20 (s, 6H), 2.09 (s, 3H), 1.76 (s, 3H), 1.72 (d, 3H) |
6a [14] | 19.45 (d, 1H) | 2.45 (q, 3H), 2.33 (s, 3H), 1.78 (d, 3H), 1.71–1.14 (m, 30H) |
1[a] [2] | 20.02 (s, 1H) | 2.62–1.15 (m, 66H) |
2[a] [4] | 19.16 (s, 1H) | 2.56–0.15 (m, 51H) |
3 [3] | 17.44 (d, 1H) | 2.37–1.20 (m, 33H), 1.80 (d, 6H) |
4a [5] | 16.56 (s, 1H) | 2.48 (s, 12H), 2.40 (s, 6H), 1.27 (d, 6H) |
CD2Cl2.