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Proposed mechanism of superoxo formation of diiron complexes with 6-Me3-TPA (Chart 2) and reactivity with 2,4-di-tert-butylphenol (DTBP). Resonance Raman data (given in cm−1) for the ν(O–O) and ν(Fe–O) frequencies and the 18O-downshifts (given in parentheses) is listed below each intermediate.
