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. Author manuscript; available in PMC: 2011 Aug 1.
Published in final edited form as: Chem Soc Rev. 2010 May 20;39(8):2768–2779. doi: 10.1039/c003079c

Scheme 8.

Scheme 8

Different protonation pathways of peroxodiiron(III) complexes. Protonation of μ-oxo (A), and μ-peroxo (B) in two different model systems. For structures of 6-Me2-BPP and 3,5-Me6-4-OMe3-TPA see Chart 2.