Table 7.

Selected bond lengths and bond angles for the [Pt(mpETSC)Cl] complex.

bond lengths (Å)		Bond angles (°)
Pt(1)–N(7)	1.979(5)	C(8)–S(1)–Pt1	95.02(11)
Pt(1)–N(1)	2.116(3)	C(2)–N(1)–C(6)	118.6(3)
Pt(1)–S(1)	2.2533(8)	C(2)–N(1)–Pt1	132.4(2)
Pt(1)–Cl(1)	2.3178(15)	C(6)–N(1)–Pt1	109.0(2)
S(1)–C(8)	1.757(3)	C(7)–N(7)–N(8)	121.8(5)
N(1)–C(2)	1.350(4)	C(7)–N(7)–Pt1	116.1(4)
N(1)–C(6)	1.370(5)	N(8)–N(7)–Pt1	121.9(3)
N(7)–C(7)	1.287(8)	C(8)–N(8)–N(7)	113.4(4)
N(7)–N(8)	1.365(6)	C(8)–N(9)–C(9)	127.1(3)
N(8)–C(8)	1.333(5)	N(1)–C(2)–C(3)	120.3(3)
N(9)–C(8)	1.331(4)	N(1)–C(2)–C(1)	119.7(3)
N(9)–C(9)	1.449(4)	C(3)–C(2)–C(1)	120.0(3)
C(1)–C(2)	1.494(4)	C(4)–C(3)–C(2)	121.1(3)
C(2)–C(3)	1.400(5)	C(3)–C(4)–C(5)	118.4(3)
C(3)–C(4)	1.370(5)	C(6)–C(5)–C(4)	119.1(3)
C(4)–C(5)	1.389(5)	N(1)–C(6)–C(5)	122.3(3)
C(5)–C(6)	1.381(5)	N(1)–C(6)–C(7)	116.5(4)
C(6)–C(7)	1.426(8)	C(5)–C(6)–C(7)	121.2(4)
C(9)–C(10)	1.491(5)	N(7)–C(7)–C(6)	117.7(6)
		N(9)–C(8)–N(8)	116.8(3)
		N(9)–C(8)–S(1)	118.8(3)
		N(8)–C(8)–S(1)	124.4(3)
		N(9)–C(9)–C(10)	113.1(3)
		N(7)–Pt1–N(1)	80.15(16)
		N(7)–Pt1–S(1)	85.25(14)
		N(1)–Pt1–S(1)	165.40(8)
		N(7)–Pt1–Cl1	174.13(12)
		N(1)–Pt1–Cl1	105.02(8)
		S(1)–Pt1–Cl1	89.57(4)