Table 1.
Donor | Acceptors | Products | Yield [%][a] |
---|---|---|---|
Gal-DNP(4) | 3SGlc-pNP (1) | Gal-β-S-1,3-Glc-pNP (9) | 85 |
3SGal-pNP (2) | Gal-β-S-1,3-Gal-pNP (12) | 83 | |
4SGlc-pNP (3) | Gal-β-S-1,4-Glc-pNP (13) | 80 | |
3SGlcNAc-pNP (5) | Gal-β-S-1,3-GlcNAc-pNP (10) | 79 | |
3SGalNAc-pNP (6) | no product | – | |
4SGlcNAc-pNP (7) | Gal-β-S-1,4-GlcNAc-pNP (11) | 47 |
Isolated yield after silica gel column chromatography.