Table 2.
Thermodynamic parameters for the binding of [(cymene)Ru(ATSC)Cl]PF6 with the HSA.
| Temperature (K) |
Ka (104 M−1) |
ΔG° (kJ/mol) |
ΔH° (kJ/mol) |
ΔS° (J/mol·K) |
|---|---|---|---|---|
| 293 | 9.09 | −28.8 | ||
| 298 | 12.1 | −29.0 | 16.7 | 152 |
| 308 | 13.1 | −30.2 |
The values of K are from the modified Stern-Volmer analysis.