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. Author manuscript; available in PMC: 2011 Jul 5.
Published in final edited form as: Inorg Chem. 2010 Jul 5;49(13):6172–6187. doi: 10.1021/ic100846b

Figure 2.

Figure 2

Molecular structures of (a) LMeFe=NAd (2), and (b) LMeFe–NHAd (3) using 50% probability thermal ellipsoids. Hydrogen atoms except the amido hydrogen are omitted. Selected bond distances [Å] and bond angles [°] for LMeFe=NAd (2): Fe1-N14, 1.6699(15); Fe1-N11, 1.9285(13); Fe1-N21, 1.9177(13), Fe1-N14-C14, 170.40(13); N11-Fe1-N14, 139.16(6); N21-Fe1-N14, 126.82(6); N11-Fe1-N21, 94.02(6). Selected bond distances [Å] and bond angles [°] for LMeFeNHAd (3): Fe1-N14, 1.860(2); Fe1-N11, 1.974(2); Fe1-N21, 1.986(2), Fe1-N14-C14, 134.7(2); N11-Fe1-N14, 145.86(8); N21-Fe1-N14, 121.04(8); N11-Fe1-N21, 93.09(7).