Table 5.
Solvent | No.b | Median (p.p.m.) | Range (p.p.m.) | Percent exceeding thresholdc | |||
ACGIH TLV | 0.01% SVP | 0.1% SVP | 1% SVP | ||||
Methylene chloride | |||||||
Measurement data | 1272 | 7.0 | 0.0004–2200 | 23 | 22 | 1.0 | 0 |
Predicted intensity | 192 | 2.8 | 0.051–160 | 4.7 | 4.2 | 0 | 0 |
1,1,1-trichloroethane | |||||||
Measurement data | 947 | 0.95 | 0.0004–1500 | 2.1 | 18 | 3.8 | 0 |
Predicted intensity | 432 | 0.67 | 0.0013–200 | 0 | 9.7 | 0.2 | 0 |
Trichloroethylene | |||||||
Measurement data | 484 | 7.0 | 0.0002–1100 | 45 | 46 | 10 | 0.2 |
Predicted intensity | 480 | 30 | 0.21–3700 | 71 | 65 | 28 | 3.1d |
To evaluate the models, a long-term personal predicted intensity was computed for each unique combination of inputs (exposure determinants and year) to the Table 4 prediction models. To avoid extrapolation errors due to limited data, years prior to 1970 were not evaluated for methylene chloride and 1,1,1-trichloroethane and years prior to 1950 were not evaluated for trichloroethylene. The midpoint of the decade was used as the year in these predictions. For example, for the methylene chloride model, there were 2 × 2 × 2 × 2 × 2 × 2 = 64 unique combinations of the exposure determinants and three decades (1970s, 1980s, and 1990s); consequently, 64 × 3 = 192 unique scenarios were evaluated.
Number of reported levels for measurement data and number of exposure determinant scenarios evaluated for predicted intensities.
Thresholds include the current ACGIH TLVs [50 p.p.m. (established in 1988), 350 p.p.m. (established in 1963), and 10 p.p.m. (established in 2006) for methylene chloride, 1,1,1-trichloroethane, and trichloroethylene, respectively] and 0.01, 0.1 and 1% of the SVP (at 25°C, is 572 386, 161 370, and 90 789 p.p.m. for methylene chloride, 1,1,1-trichloroethane, and trichloroethylene, respectively).
All scenarios exceeding 1% of the SVP for trichloroethylene were from the 1950s–1970s.