Table 2.
13C NMR data for 1-4 in acetone-d6 (100 MHz, unless otherwise noted)
C | 1 | 2 | 3 | 4a |
---|---|---|---|---|
2 | 117.2 CH | 170.6 C | 169.4 C | 118.5 CH |
3 | 127.9 C | 129.8 C | 129.7 C | 129.3 C |
4 | 127.9 C | 151.0 C | 152.5 C | 129.3 C |
5 | 117.2 CH | 50.7 CH2 | 81.5 CH | 118.5 CH |
6 | 168.8 C | 171.6 C | 172.0 C | 171.9 C |
7 | 39.8 CH2 | 42.1 CH2 | 42.6 CH2 | 73.9 CH |
1′ | 124.8 C | 126.6 C | 126.5 C | 131.5 C |
2′,6′ | 130.6 CH | 131.7 CH | 132.1 CH | 129.9 CH |
3′,5′ | 115.4 CH | 115.9 CH | 116.1 CH | 116.8 CH |
4′ | 156.4 C | 157.1 C | 157.4 C | 159.1 C |
1″ | 125.6 C | 123.8 C | 123.9 C | 126.5 C |
2″,6″ | 129.6 CH | 131.9 CH | 131.8 CH | 130.8 CH |
3″,5″ | 115.1 CH | 116.2 CH | 116.4 CH | 116.3 CH |
4″ | 156.4 C | 158.4 C | 158.9 C | 157.9 C |
1‴ | 125.6 C | 124.6 C | 123.9 C | 126.5 C |
2‴,6‴ | 129.6 CH | 130.6 CH | 132.2 CH | 130.8 CH |
3‴,5‴ | 115.1 CH | 116.4 CH | 116.4 CH | 116.3 CH |
4‴ | 156.4 C | 160.2 C | 160.2 C | 157.9 C |
125 MHz