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. Author manuscript; available in PMC: 2011 Aug 11.
Published in final edited form as: J Am Chem Soc. 2010 Aug 11;132(31):10634–10637. doi: 10.1021/ja104254d

Scheme 1.

Scheme 1

NHC–Cu-Catalyzed Boronate Additions to Disubstituted Allylic Carbonatesa

a All conv >98% by analysis of 400 MHz 1H NMR spectra of unpurified mixtures; >98% SN2′ in all cases. Er determined by GLC analysis (see the SI for details).