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. Author manuscript; available in PMC: 2011 Jul 28.
Published in final edited form as: J Am Chem Soc. 2010 Jul 28;132(29):9994–9996. doi: 10.1021/ja104090m

Figure 3.

Figure 3

Flavin substituent effects on Dkcat. Reactions with IPP and (R)-[2-2H]-IPP (open and filled circles, respectively, in panel B) were carried out under pseudo-first order conditions as described in the supporting information. (A) Calculated Dkcat from the data in panel (B). (B) Hammett plots: ρ = −2.5(4) and −2.7(5) for IPP and (R)-[2-2H]-IPP, respectively.