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. 2010 Jun 11;285(33):25531–25537. doi: 10.1074/jbc.M110.123984

TABLE 1.

Rate constants observed for the oxidation of the low spin hemes during oxidation of fully reduced NOR by NO

NO concentration Rate constants % of Total amplitude
560 nm (heme b) 550 nm (heme c)
s1
1.5 mm NO, pH 7.5 50 10 50
3 90 50
75 μm NO, pH 7.5 120 10 55
12 90 45
1.5 mm NO, pH 6.0 150 ∼10a 40
6 ∼90a 60
75 μm NO, pH 6.0 ∼500 35 60
100 65 40

a Not detected at 560 nm, amount of heme b oxidized estimated from other wavelengths.