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. Author manuscript; available in PMC: 2011 Aug 18.
Published in final edited form as: J Am Chem Soc. 2010 Aug 18;132(32):10973–10975. doi: 10.1021/ja103805s

Table I.

Observed compounds resulting from the reaction between diphenylphophine selenide and metal carboxylates.

δ
(ppm)a 		δ
(ppm)a
2 RCOOH 12.2 - 12.5b,e 7 Ph2PH - 40.2c,e 215 Hz 1J(31P - 1H)
graphic file with name nihms225142t1.jpg 98.9c,g graphic file with name nihms225142t2.jpg 77.1c,h 875 Hz 1J(31P - 77Se)
graphic file with name nihms225142t3.jpg 22.0c,e 441 Hz 1J(31P - 1H) 12 Ph2PPPh2 - 14.5c,e,f
graphic file with name nihms225142t4.jpg 168.9d,e graphic file with name nihms225142t5.jpg 25.7c,e,f
R=C17H33
a

All spectra were recorded in toluene-d8

b

1H NMR

c

31P NMR

d

13C NMR.

e

Verified by addition of authentic sample.

f

Isolated diffraction quality single crystals from the reaction.

g

Chemiker Zeitung 1982, 391-395.

h

Chem. Commun., 2005, 2692-2694.