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. Author manuscript; available in PMC: 2010 Aug 20.
Published in final edited form as: Inorg Chem. 2009 Aug 3;48(15):7341–7349. doi: 10.1021/ic900796n

Table 2.

Percent Conversions of Multiple Postsynthetic Modification Reactions with IRMOF-3 and Different Anhydrides or Isocyanates As Determined by 1H NMRa

% conversion
IRMOF-3- reagentsb AM9 UR3 or
URPh		 URAl AMCrot
AM9/UR3 (1)DA 21±1 21±3
(2) PI
AM9/UR3/URAl (1)DA 21±4 22±1 23±1
(2) PI
(3) AI
AM9/UR3/URAl/AMCrot-a (1) DA 24±4 18±6 21±3 17± 1
(2) PI
(3) AI
(4) CA
AM9/UR3/URAl/AMCrot-bc (1) DA 23±1 8±2 13±2 13±1
(2) PI
(3) AI
(4) CA
AM9/URPh (1)DA 24±2 32±2
(2) PhI
AM9/URPh/URAl (1)DA 26±5 28±2 20±3
(2) PhI
(3) AI
AM9/URPh/URAl/AMCrot (1) DA 20±1 30±1 20±1 8±1
(2) PhI
(3) AI
(4) CA
a

Values listed are an average (with standard deviations) of at least three independent experiments.

b

AI = allyl isocyanate; CA = crotonic anhydride; DA = decanoic anhydride; PI = propyl isocyanate; PhI = phenyl isocyanate.

c

Propyl and allyl isocyanate reaction times reduced to 3 h each.