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. Author manuscript; available in PMC: 2011 Jul 21.
Published in final edited form as: J Am Chem Soc. 2010 Jul 21;132(28):9774–9781. doi: 10.1021/ja102524v

Scheme 2.

Scheme 2

Acid-base equilibria involving 2e (in the box) and hydrogen peroxide to produce species that react pairwise to afford Oxidized TAML (see Scheme 3). Numerals at the two-sided arrows 1–6 correspond to the rate constants k1–k6, respectively.

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