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The minimum flip angle βmin required to saturate Mz,γ-ATP to below 5% of its equilibrium value over a bandwidth of 40Hz with the corresponding PCr spill-over Q for constant (m=1) and amplitude modulated (m=5) irradiation at 9cm depth and at the surface. Close to the coil, the flip-angle is about 6-times higher, increasing the spillover irradiation and reducing Q.