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. Author manuscript; available in PMC: 2011 Jul 1.
Published in final edited form as: Environ Sci Technol. 2010 Jul 1;44(13):4951–4957. doi: 10.1021/es100094f

TABLE 2.

Applied mass (μg), total mass wash-off (μg), 10 liter mass wash-off (μg), and EMC (μg/L) for rainfall simulations utilizing formulated product sand neat-grade pyrethroids and surfactant. Mean result of two simultaneous replicates and (standard deviation)

Formulated Product Experiment (Intensity/Set Time)
25/1.5h
25/24h
25/7d
25/7d 2nd
25/21d 3rd
25/49d 4th
50/1.5h
50/24h
β Cyfluthrin SC
Applied Mass 15,300 (247) 14,600 (233) 12,200 (27.2) a a a 13,900 (166) 15,300 (552)
Total Mass Washoff 8,290 (5,340) 2,650 (776) 998 (8.64) 151 (66.3) 41.6 (11.3) 15.1 (0.106) 4,830 (139) 4,150 (134)
Mass Washoff at 10 L 8,200 (5,340) 2,590 (758) 977 (8.77) 140 (64.9) 35.9 (10.8) 12.5 (0.144) 4,660 (149) 3,970 (137)
EMC 587 (387) 180 (51.6) 71.3 (1.1) 10.4 (4.71) 2.95 (0.811) 1.07 (0.00210) 174 (5.45) 143 (1.56)
Esfenvalerate EC
Applied Mass 1,750 (60.7) 1,860 (88.7) 2,010 (51.3) a a a 1,790 (84.0) 1,920 (4.67)
Total Mass Washoff 25.5 (9.95) 22.6 (0.109) 15.1 (1.84) 17.9 (8.2) 8.04 (2.79) 1.44 (0.0677) 26.4 (0.483) 41.4 (1.61)
Mass Washoff at 10 L 22.3 (8.83) 18.0 (0.359) 13.4 (1.33) 14.8 (7.11) 6.89 (2.59) 1.16 (0.111) 16.2 (1.22) 22.6 (1.46)
EMC 1.87 (0.741) 1.57 (0.0321) 1.10 (0.0695) 1.22 (0.561) 0.578 (0.202) 0.101 (0.00435) 0.955 (0.0121) 1.44 (0.0632)
λ Cyhalothrin EC
Applied Mass 1,090 (6.67) 1,470 (1.63) 1,170 (18.7) b b b 1,060 (26.4) 1,410 (13.3)
Total Mass Washoff 46.1 (4.13) 35.7 (3.12) 2.83 (0.0908) 50.7 (7.56) 26.2 (3.23)
Mass Washoff at 10 L 40.5 (4.42) 28.5 (2.37) 2.47 (0.119) 31.4 (5.36) 16.6 (1.99)
EMC 3.45 (0.388) 2.47 (0.218) 0.214 (0.0130) 1.75 (0.243) 0.897 (0.104)
2007 Bifenthrin CE
Applied Mass 30,000 (247) 31,300 (742) b b b b 31,200 (1,630) c b
Total Mass Washoff 1,510 (484) 456 (147) 646 (531) c
Mass Washoff at 10 L 1,500 (484) 438 (151) 607 (530) c
EMC 111 (41.9) 33.1 (11.6) 22.7 (29.3) c
2009 Bifenthrin CE
Applied Mass 32,600 (813) b b b b b 32,000 (389) b
Total Mass Washoff 490 (353) 702 (139)
Mass Washoff at 10 L 465 (347) 642 (131)
EMC 33.4 (24.3) 24.0 (4.93)
Neat-Grade Experiments (Intensity/Set Time)
25/1.5h 25/1.5h 25/1.5h
Bifenthrin & LAS Neat Grade Bifenthrin Neat Grade Esfenvalerate Neat Grade
Applied Mass 30,000 (0.0) 29,200 (0.0) 1,890 (0.0)
Total Mass Washoff 257 (15.1) 73.1 (19.2) 65.5 (1.28)
Mass Washoff at 10 L 243 (10.1) 61.4 (18.1) 53.5 (0.0784)
EMC 19.2 (0.598) 4.98 (1.22) 4.46 (0.00320)
a

initial application was that of corresponding 25/1.5h experiment

b

experiment not conducted

c

result of 4 replicates