Voltage- (A) and pH-dependence (B) of the
SRI and pSRII-F86D photocurrents. Triangles represent data points of
pSRII-F86D (normalized to SRI current at 0 mV), squares are indicative
for SRI. Both pigments show a steep linear current/voltage-dependence
and the signals do not invert at any observed potential
(A). The pH-dependence (B) was recorded
at a constant membrane potential of −20 mV (SRI) or −40 mV
(pSRII-F86D). In the case of pSRII-F86D, only a slight linear increase
of the photocurrent with increasing proton concentration is visible,
whereas SRI shows a sigmoidal pH dependence. The deflection point
corresponds to the pKa 7.2 (Boltzmann fit; Imin =
−0.16 ± 0.2, Imax = 4.0 ± 0.3, pH
(Imax/2) = 7.2 ± 0.1).