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. Author manuscript; available in PMC: 2011 Aug 16.
Published in final edited form as: Angew Chem Int Ed Engl. 2010 Aug 16;49(35):6134–6138. doi: 10.1002/anie.201002228

TABLE 1.

KIE values (kH/kD) for aerial oxidation and oxidation by superoxide radicals for deuterated radical oxidant probes.

graphic file with name nihms-227420-t0001.jpg
Probe Product kH/kD
Aerial
oxidation[a]
Oxidation
by (O2·−)[b]
graphic file with name nihms-227420-t0002.jpg graphic file with name nihms-227420-t0003.jpg 4.7 2.5
graphic file with name nihms-227420-t0004.jpg graphic file with name nihms-227420-t0005.jpg 3.7 2.6
graphic file with name nihms-227420-t0006.jpg graphic file with name nihms-227420-t0007.jpg 4.1 2.7
graphic file with name nihms-227420-t0008.jpg graphic file with name nihms-227420-t0009.jpg 4.7 2.8
graphic file with name nihms-227420-t0010.jpg graphic file with name nihms-227420-t0011.jpg 2.1 1.7
[a]

Measured by using a 60 μm concentration of 1–10 in PBS at 25 °C (see the Supporting Information).

[b]

kH and kD were determined following the method described by Finkelstein et al.[12] (see the Supporting Information). Cy=cyanine dye, DHE=dihydroethidium, DDE=dideuteroethidium, DHR=dihydrorhodamine, DDR=dideuterorhodamine.