Table 1.
Substrate | Substrate Class (Hperoxo) | Substrate Class (Q) | Dipole Moment (D)a |
---|---|---|---|
CH4b | nrc | II | 0 |
C2H6d | nde | 1 | 0 |
Et2Of | II | II | 1.10 |
HCOONa | III | nrc | 1.41g |
CH3CH2OH | II | I | 1.69 |
CH3OH | II | I | 1.70 |
CH3CH2CHO | III | I or IIh | 2.52 |
CH3CHO | III | II | 2.69 |
CH3NO2 | III | III | 3.46 |
CH3CN | III | III | 3.92 |
Data from (63).
Data from (23).
No reaction.
Data from (39).
Not determined.
Data from (26).
This value was determined for HCOOH but should approximate that of HCOONa.
For CH3CH2CHO, the KIE was not determined but a linear dependence on substrate concentration was observed, designating this substrate as Class I or Class II.