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Rate Constants for Class II Substrates of Hperoxo
| Substrate | kobs (M-1 s-1) | KIEappa |
|---|---|---|
| (CH3CH2)2Ob | 17 ± 1 | |
| (CD3CD2)2Ob | 8.7 ± 0.1 | 2.02 ± 0.2 |
| CH3CH2OH | 12.13 ± 0.01 | |
| CD3CD2OH | 3.93 ± 0.06 | 3.09 ± 0.05 |
| CH3OH | 2.4 ± 0.6 | |
| CD3OD | 1.54 ± 0.02 | 1.6 ± 0.4 |
Apparent kinetic isotope effect, kH/kD.
Data from (26).
