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. Author manuscript; available in PMC: 2011 Sep 1.
Published in final edited form as: J Am Chem Soc. 2010 Sep 1;132(34):12150–12154. doi: 10.1021/ja105834t

Chart 1.

Chart 1

Limitations of the presented fluorination reaction.a a) The fluorination was attempted from the corresponding arylstannane: 5.0 mol% Ag2O, 1.5 equiv F-TEDA-PF6, 2.0 equiv NaHCO3, 1.0 equiv NaOTf, 5.0 equiv MeOH, acetone, 65 °C, 4 h. b) 20 mol% of AgOTf, 2 equiv of NaOTf and 2 equiv of F-TEDA-PF6 were used at 90 °C.