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. Author manuscript; available in PMC: 2011 Sep 15.
Published in final edited form as: J Am Chem Soc. 2010 Sep 15;132(36):12534–12536. doi: 10.1021/ja1050814

Figure 1.

Figure 1

Selected enediynes and biosynthesis of the aromatic acid moieties: (A) the enediyne chromophores of C-1027 (1), NCS (2), and MDP (3) with the aromatic acid moieties highlighted in red; (B) biosynthesis of the naphthoic acid moiety of 2; and (C) early and (D) revised biosynthesis of the salicylyl moiety of 3.