Table 2.
| ||||
---|---|---|---|---|
entry | HetAr-BF3K | yield (%) | ||
1 | X = OMs | 2a | 93 | |
X = OPiv | 78 | |||
2 | X = OMs | 2b | 90 | |
X = OPiv | 75a | |||
3 | X = OMs | 2c | 64 | |
X = OPiv | 26a, b | |||
4 | X = OMs | 2d | 82 | |
X = OPiv | 60 | |||
5 | X = OMs | 2e | 69 | |
X = OPiv | 32b | |||
6 | X = OMs | 2f | 83 | |
X = OPiv | 26b | |||
7 | X = OMs | 2g | 79 | |
8 | X = OMs | 2h | 95 | |
9 | X = OMs | 2i | 42 | |
10 | X = OMs | 2j | 81 | |
11 | X = OMs | 2k | 91 | |
12 | X = OMs | 2l | 74 | |
13 | X = OMs | 2m | 90c |
Dioxane/H2O (1/1), c = 0.05 and t-BuPCy2.
Relative GC yield determined using dodecane as an internal standard.
With 10% of impurities that cannot be separated.