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. Author manuscript; available in PMC: 2011 Sep 17.
Published in final edited form as: Org Lett. 2010 Sep 17;12(18):4022–4025. doi: 10.1021/ol101592r

Table 2.

Scope of Potassium Heteroaryltrifluoroborates

graphic file with name nihms229926u3.jpg
entry HetAr-BF3K yield (%)
1 graphic file with name nihms229926t1.jpg X = OMs 2a 93
X = OPiv 78
2 graphic file with name nihms229926t2.jpg X = OMs 2b 90
X = OPiv 75a
3 graphic file with name nihms229926t3.jpg X = OMs 2c 64
X = OPiv 26a, b
4 graphic file with name nihms229926t4.jpg X = OMs 2d 82
X = OPiv 60
5 graphic file with name nihms229926t5.jpg X = OMs 2e 69
X = OPiv 32b
6 graphic file with name nihms229926t6.jpg X = OMs 2f 83
X = OPiv 26b
7 graphic file with name nihms229926t7.jpg X = OMs 2g 79
8 graphic file with name nihms229926t8.jpg X = OMs 2h 95
9 graphic file with name nihms229926t9.jpg X = OMs 2i 42
10 graphic file with name nihms229926t10.jpg X = OMs 2j 81
11 graphic file with name nihms229926t11.jpg X = OMs 2k 91
12 graphic file with name nihms229926t12.jpg X = OMs 2l 74
13 graphic file with name nihms229926t13.jpg X = OMs 2m 90c
a

Dioxane/H2O (1/1), c = 0.05 and t-BuPCy2.

b

Relative GC yield determined using dodecane as an internal standard.

c

With 10% of impurities that cannot be separated.