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. Author manuscript; available in PMC: 2011 Sep 8.
Published in final edited form as: J Am Chem Soc. 2010 Sep 8;132(35):12214–12215. doi: 10.1021/ja105591q

Figure 1.

Figure 1

Depiction of the active sites of CDO derived from X-ray crystallography for (a) the iron(II) resting state (b) the Cys-bound form and (c) a trapped persulfenate complex; (d) CDO reaction scheme.