Table 2.
Enthalpy ΔH0 in kcal/mol and entropy ΔS0
| For target Gc | Poly-pyrrole grafting | Thiols self-assembly | |||||
|---|---|---|---|---|---|---|---|
| Probes | #MM | ΔH0 | ΔS0 | ΔG0 | ΔH0 | ΔS0 | ΔG0 |
| G | PM | –21.2 | –33.4 | –10.9 | –22.6 | –32.1 | –12.7 |
| A | 1 MM | –32.6 | –71.7 | –10.4 | –42.9 | –98.3 | –12.4 |
| TG | 1 MM | –27.2 | –54.0 | –10.5 | –34.4 | –71.1 | –12.4 |
| TA | 2 MM | –36.8 | –86.6 | –10.0 | –54.4 | –138.0 | –11.6 |
Measured in cal/mol/K from linear fits of the collapsed master curves for the different probes and grafting chemistry (errors from the fits are ∼1%). Corresponding free energy ΔG0 in kcal/mol calculated at 37°C.