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. Author manuscript; available in PMC: 2011 Sep 15.
Published in final edited form as: Anal Chem. 2010 Sep 15;82(18):7634–7640. doi: 10.1021/ac1013767

Table 1.

Silver Ion Selectivities ( logKAg,Jpot) of Fluorous Ionophore-Doped Electrode Membranes Based on Perfluoroperhydrophenanthrene with Different Ratios of Ionophore and Ionic Sitesa

Ionophore Ionophore/Ionic Site Ratio Ag+ selectivity ( logKAg,Jpot)
K+ Na+ Cu2+
Ag-2 3:1 −5.97±0.07 −7.60±0.09 −8.09±0.19
5:1 −8.12±0.08 −9.06±0.15 −10.09±0.18
Ag-3 3:1 −9.45±0.15 −10.93±0.21 −11.22±0.21
Ag-4 2:1 −9.11±0.21 −10.35±0.22 −10.50±0.25
3:1 −11.60±0.13 −12.94±0.14 −13.04±0.22
a

The concentration of ionic sites, 3, for all electrode membranes was 1.0 mM.