Table 1.
Silver Ion Selectivities ( ) of Fluorous Ionophore-Doped Electrode Membranes Based on Perfluoroperhydrophenanthrene with Different Ratios of Ionophore and Ionic Sitesa
| Ionophore | Ionophore/Ionic Site Ratio | Ag+ selectivity ( ) | ||
|---|---|---|---|---|
| K+ | Na+ | Cu2+ | ||
| Ag-2 | 3:1 | −5.97±0.07 | −7.60±0.09 | −8.09±0.19 |
| 5:1 | −8.12±0.08 | −9.06±0.15 | −10.09±0.18 | |
| Ag-3 | 3:1 | −9.45±0.15 | −10.93±0.21 | −11.22±0.21 |
| Ag-4 | 2:1 | −9.11±0.21 | −10.35±0.22 | −10.50±0.25 |
| 3:1 | −11.60±0.13 | −12.94±0.14 | −13.04±0.22 | |
The concentration of ionic sites, 3, for all electrode membranes was 1.0 mM.