Table 2.
Selected bond lengths (Å) and angles (°) for complex 1 a.
| Cd(1)-O(1) | 2.373(2) | Cd(2)-O(11) | 2.190(3) |
| Cd(1)-O(3) | 2.375(3) | C(1)b-O(1) | 1.242(5) |
| Cd(1)-O(4) | 2.557(3) | C(1)b-O(2) | 1.253(5) |
| Cd(1)-N(1) | 2.465(3) | C(11)c-O(11) | 1.264(5) |
| Cd(2)-O(1) | 2.550(2) | C(11)c-O(12) | 1.234(5) |
| Cd(2)-O(2) | 2.311(4) | ||
| O(1)-Cd(1)-O(1′) | 153.4(1) | O(1)-Cd(2)-O(1′′) | 156.8(1) |
| O(1)-Cd(1)-N(1′) | 119.8(1) | O(1)-Cd(2)-O(2) | 52.9(1) |
| O(3)-Cd(1)-O(3′) | 87.7(2) | O(2)-Cd(2)-O(2′′) | 94.2(2) |
| O(3)-Cd(1)-O(4′) | 155.3(1) | O(2)-Cd(2)-O(11) | 129.6(1) |
| O(4)-Cd(1)-O(4′) | 75.3(2) | O(11)-Cd(2)-O(11′′) | 117.6(2) |
| O(4)-Cd(1)-N(1′) | 84.8(1) | O(11)-Cd(2)-O(2′′) | 93.1(1) |
| N(1)-Cd(1)-N(1′) | 147.5(2) | O(1)-C(1)b-O(2) | 121.2(4) |
| N(1)-Cd(1)-O(4) | 69.3(1) | O(11)-C(11)c-O(12) | 123.0(4) |
aSymmetry transformations used to generate equivalent atoms:(′) y, x, −z; (′′) –y + 1, −z + 1, −z + 1/2.
bThis carbon atom (not labeled in Figure 1) belongs to the carboxylate group of the bicinate(−1) ligand.
cThis carbon atom (not labeled in Figure 1) belongs to the carboxylate group of the benzoate ligand.