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. Author manuscript; available in PMC: 2011 Oct 13.
Published in final edited form as: J Am Chem Soc. 2010 Oct 13;132(40):14092–14103. doi: 10.1021/ja1036644

Figure 10.

Figure 10

a) Plot of the 4s core electron binding energy of Pda (solid) and Pdb (dashed) as a function of reaction progress for monometallic reductive elimination via a Pd(I)/Pd(III) mixed valence species (Figure 9, path 3). b) Plot of electron binding energy of Pda and Pdb as a function of reaction progress for monometallic reductive elimination from a Pd(II) / Pd(IV) mixed valence species (Figure 9, path 5). c) Plot of electron binding energy of Pda and Pdb as a function of reaction progress for calculated bimetallic reductive elimination (Figure 5).