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Potential pathways from dinuclear Pd complexes. Path 3: Monometallic reductive elimination to form a Pd(I)/Pd(III) mixed valence complex and 2 followed by comproportionation to afford Pd(II). Path 4: Computed low-energy pathway for reductive elimination (Figure 6). Path 5: Disproportionation to a Pd(II)/Pd(IV) mixed valence complex followed by monometallic reductive elimination.
