Table 2.
13C NMR Spectroscopic Data of 1–6
| position | δC, mult. | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 a | 2 a | 3 b | 4 a | 5 b | 6 b | |||||||
| 1 | 83.0 | CH | 83.1 | CH | 84.7 | CH | 83.0 | CH | 83.6 | CH | 83.9 | CH |
| 2 | 196.0 | qC | 196.0 | qC | 197.6 | qC | 196.0 | qC | 72.9 | CH | 73.0 | CH |
| 3 | 124.2 | CH | 124.1 | CH | 126.5 | CH | 124.3 | CH | 126.8 | CH | 127.3 | CH |
| 4 | 164.7 | qC | 165.1 | qC | 162.7 | qC | 164.7 | qC | 134.9 | qC | 135.2 | qC |
| 5 | 41.7 | CH | 41.7 | CH | 42.5 | CH | 41.7 | CH | 41.4 | CH | 42.3 | CH |
| 6 | 25.4 | CH2 | 25.3 | CH2 | 26.2 | CH2 | 25.5 | CH2 | 25.7 | CH2 | 26.2 | CH2 |
| 7 | 77.3 | CH | 77.2 | CH | 78.7 | CH | 77.3 | CH | 78.8 | CH | 79.3 | CH |
| 8 | 47.5 | qC | 47.4 | qC | 46.5 | qC | 47.3 | qC | 48.1 | qC | 46.4 | qC |
| 9 | 44.4 | CH | 44.2 | CH | 45.9 | CH | 44.5 | CH | 45.1 | CH | 45.7 | CH |
| 10 | 45.3 | qC | 45.3 | qC | 45.7 | qC | 45.2 | qC | 42.1 | qC | 41.7 | qC |
| 11 | 108.8 | qC | 108.7 | qC | 111.0 | qC | 108.9 | qC | 110.7 | qC | 111.3 | qC |
| 12 | 79.3 | CH | 79.5 | CH | 80.3 | CH | 79.2 | CH | 80.2 | CH | 80.4 | CH |
| 13 | 31.4 | CH | 31.2 | CH | 33.0 | CH | 31.4 | CH | 32.7 | CH | 33.3 | CH |
| 14 | 45.5 | CH | 44.8 | CH | 48.4 | CH | 45.6 | CH | 45.7 | CH | 48.4 | CH |
| 15 | 71.0 | CH | 71.0 | CH | 71.8 | CH | 69.4 | CH | 73.0 | CH | 70.6 | CH |
| 16 | 167.0 | qC | 167.0 | qC | 168.4 | qC | 167.3 | qC | 167.7 | qC | 168.7 | qC |
| 18 | 23.0 | CH3 | 23.0 | CH3 | 22.6 | CH3 | 23.0 | CH3 | 21.0 | CH3 | 21.5 | CH3 |
| 19 | 10.1 | CH3 | 10.1 | CH3 | 11.2 | CH3 | 10.0 | CH3 | 11.0 | CH3 | 11.3 | CH3 |
| 20 | 71.0 | CH2 | 71.9 | CH2 | 71.6 | CH2 | 71.0 | CH2 | 71.4 | CH2 | 71.9 | CH2 |
| 21 | 14.1 | CH3 | 14.1 | CH3 | 16.1 | CH3 | 14.5 | CH3 | 15.6 | CH3 | 15.9 | CH3 |
| 1′ | 171.4 | qC | 171.4 | qC | 176.7 | qC | 175.7 | qC | 171.4 | qC | 175.8 | qC |
| 2′ | 80.7 | qC | 80.6 | qC | 75.6 | qC | 41.0 | CH | 81.1 | qC | 41.9 | CH |
| 3′ | 30.1 | CH2 | 31.7 | CH2 | 34.2 | CH2 | 26.5 | CH2 | 31.4 | CH2 | 27.4 | CH2 |
| 4′ | 7.2 | CH3 | 7.2 | CH3 | 8.8 | CH3 | 11.5 | CH3 | 7.5 | CH3 | 12.2 | CH3 |
| 5′ | 21.1 | CH3 | 21.1 | CH3 | 26.1 | CH3 | 16.0 | CH3 | 21.0 | CH3 | 16.5 | CH3 |
| 1″ | 170.1 | qC | 170.3 | qC | 169.9 | qC | ||||||
| 2″ | 20.9 | CH3 | 20.3 | CH3 | 21.0 | CH3 | ||||||
Measured in CDCl3;
Measured in pyridine-d5