Table 2.
Correction method A1 | Correction method B1 | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Element | Median uncorrected concentration (n=150) |
median | mean | sd | Samples with detectable element (%) |
Median uncorrected concentration (n=15) |
median | mean | sd | Samples with detectable element (%) |
R2 |
Al | 72.13 | −8.13 | 14.35 | 59.60 | 1 | 61.40 | −10.85 | −12.02 | 20.26 | 0 | 0.39 |
Ba | 19.89 | 11.43 | 11.74 | 3.62 | 99 | 20.03 | 0.96 | 0.69 | 2.62 | 13 | 0.51 |
Ca | 13 159.67 | 6 042.05 | 6 062.44 | 2 003.74 | 83 | 13 265.95 | 5 699.21 | 5 462.04 | 1 713.48 | 73 | 0.85 |
Cd | 0.33 | 0.24 | 0.33 | 0.46 | 100 | 0.31 | −0.07 | −0.15 | 0.18 | 0 | 0.76 |
Ce | 0.37 | 0.24 | 0.24 | 0.16 | 76 | 0.41 | −0.03 | −0.04 | 0.10 | 7 | 0.19 |
Co | 1.43 | −0.73 | −0.76 | 0.67 | 0 | 1.48 | 1.31 | 1.29 | 0.25 | 100 | 0.64 |
Cr | 0.43 | 0.01 | 0.05 | 0.28 | 3 | 0.40 | −0.16 | −0.43 | 1.03 | 7 | 0.45 |
Cs | 0.07 | 0.06 | 0.10 | 0.30 | 61 | 0.06 | 0.03 | 0.03 | 0.03 | 80 | 0.47 |
Cu | 56.45 | 48.99 | 50.63 | 14.12 | 100 | 60.01 | 46.53 | 45.45 | 12.30 | 100 | 0.91 |
Fe | 9 317.13 | 9 237.96 | 9 797.48 | 3 481.14 | 100 | 11 526.76 | 11 261.81 | 10 124.47 | 3 679.06 | 100 | 1.00 |
K | 87 441.07 | 87 202.97 | 95 169.20 | 37 889.52 | 100 | 92 189.82 | 58 085.18 | 58 665.40 | 18 807.63 | 100 | 0.96 |
Li | 0.53 | 0.28 | 13.42 | 84.72 | 32 | 0.78 | 0.63 | 35.65 | 135.66 | 87 | 1.00 |
Mg | 4 672.12 | 2 943.92 | 3 016.80 | 666.84 | 99 | 5 027.94 | 3 559.58 | 3 570.04 | 803.53 | 100 | 0.95 |
Mn | 35.83 | 19.31 | 18.53 | 5.89 | 97 | 38.34 | 0.49 | 0.33 | 4.55 | 0 | 0.26 |
Mo | 0.20 | 0.02 | 0.43 | 1.66 | 19 | 0.56 | −0.25 | −0.22 | 0.34 | 0 | 0.05 |
Na | 74 889.37 | 71 689.86 | 75 469.07 | 26 607.75 | 100 | 80 687.55 | 51 973.43 | 52 866.97 | 15 005.55 | 100 | 0.94 |
Ni | 1.27 | 0.46 | 1.58 | 5.98 | 18 | 1.65 | −0.72 | 3.37 | 11.97 | 13 | 1.00 |
P | 25 068.88 | 24 841.72 | 26 051.10 | 7 178.15 | 100 | 27 198.43 | 25 971.20 | 25 773.40 | 6 260.10 | 100 | 0.99 |
Pb | 1.83 | 0.76 | 1.33 | 1.87 | 10 | 1.61 | 0.30 | 0.88 | 2.90 | 27 | 0.95 |
Rb | 84.83 | 84.59 | 96.18 | 45.31 | 100 | 96.30 | 59.57 | 57.23 | 21.04 | 100 | 0.96 |
S | 3 644.95 | 3 011.47 | 3 169.25 | 1 446.07 | 100 | 3 897.68 | 2 647.47 | 2 572.00 | 602.73 | 100 | 0.97 |
Sb | 0.09 | 0.07 | 0.11 | 0.15 | 9 | 0.07 | −0.09 | −0.06 | 0.23 | 0 | 0.70 |
Sr | 18.59 | 6.65 | 6.77 | 2.58 | 56 | 19.98 | 4.58 | 4.47 | 2.98 | 33 | 0.94 |
Ti | 0.82 | −0.46 | −0.24 | 1.23 | 0 | 0.62 | −1.10 | −1.07 | 1.65 | 0 | 0.62 |
Tl3 | 6.00 | 4.20 | 3.78 | 3.11 | 16 | 6.67 | 4.72 | 4.05 | 2.24 | 20 | 0.41 |
U3 | 7.75 | −0.37 | 0.15 | 3.64 | 2 | 5.51 | −3.53 | −3.74 | 2.58 | 0 | 0.40 |
V | 0.16 | −0.01 | 0.00 | 0.07 | 1 | 0.14 | −0.01 | −0.04 | 0.11 | 0 | 0.37 |
Zn | 213.59 | 203.26 | 217.82 | 91.48 | 87 | 226.43 | 142.16 | 119.67 | 121.15 | 80 | 0.82 |
Statistics for correction methods A and B are based on 150 and 15 samples respectively.
Pearson’s correlation coefficient between NBS element concentrations calculated using method A and B on the same samples (n=15)
Expressed in picograms/spot