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. 2010 Sep 13;11(9):3226–3251. doi: 10.3390/ijms11093226

Table 1.

Details of the ceria nanomaterials UV-Vis absorption analyses.

References Preparation Procedure Sample Band Gap a(eV)
Ed Ei
e[2] Polyol Polycrystalline CeO2 3.19 N.A.
CeO2 nanospheres (80–100 nm), 3.46
Microrods (d WD several100 nm; d L 15 to 20 μm, d AR 25 to 33), 3.62
Spindle-like (d WD several 100 nm, d L 2 to 4 μm, d AR 4-8) 3.36
[49] Hydrothermal Spindle like (d WD 800 nm and d L 5 μm) 3.55 N.A.
[50] Hydrothermal CeO2 prism-like mesocrystal
Bulk CeO2
3.02
3.19
N.A.
[51] Spray pyrolysis CeO2 films (cerium chloride) (cerium nitrate) 3.6
3.53
N.A.
[52] Electron beam evaporation; Ion beam assisted deposition Nanostructured CeO2−x 3.48 3.18
e[11] Ultrasonication CeO2 nanorods (d AR 10 to 15:1, d L 50–150 nm) 2.9 2.67
[53] Microemulsion Ceria ultrafine nanostructure 3.44
2.6
2.87
2.73
[54] Pulsed electron beam CeO2 nanocrystalline films N.A. 2.58
[5658] Physical vapor-deposited CeO2 films N.A. 3.15–3.5
[59] Spray deposition CeO2 films N.A. 3.06–3.08
[60] Sol-gel method CeO2 films N.A. 3.03–3.07

Notes:

a

According to the solid band theory for a semiconductor ()n = constant(Eg), where is the photo energy, α is the absorption coefficient, constant is relative to the material, Eg is the band gap;

b

Ed: Band gap energy for direct transitions in where n = 2; Ei: Band gap energy for indirect transitions in where n = 1/2;

d

AR = aspect ratio; L = length; N.A. = not available; WD = width;

e

Surfactant method.